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chemical-engineering
Quiz 10
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Q.1
Pick out the correct statement.
If an insoluble gas is passed through a volatile liquid placed in a perfectly insulated container, the temperature of the liquid will increase
A process is irreversible as long as Δ S for the system is greater than zero
The mechanical work done by a system is always equal to ∫P.dV
The heat of formation of a compound is defined as the heat of reaction leading to the formation of the compound from its reactants
Q.2
Pick out the wrong statement.
Surface tension of a substance vanishes at critical point, as there is no distinction between liquid and vapour phases at its critical point
Entropy of a system decreases with the evolution of heat
Change of internal energy is negative for exothermic reactions
The accentric factor for all materials is always more than one
Q.3
Ideal gas law is applicable at
Low T, low P
High T, high P
Low T, high P
High T, low P
Q.4
Absorption/evolution of heat during conversion of a substance from one allotropic form to another is termed as the heat of
Sublimation
Fusion
Transition
Vaporisation
Q.5
Work done may be calculated by the expression ∫p dA for __________ processes.
Non-flow reversible
Adiabatic
Both A and B
Neither A nor B
Q.6
Generation of heat by friction is an example of a/an __________ change.
Isothermal
Irreversible
Adiabatic
Reversible
Q.7
Rotary lime kiln is an example of a/an __________ system.
Closed
Open
Isolated
Non-thermodynamic
Q.8
The equation, C
p
- C
v
= R, is true for __________ gas.
No
Any real
Only ideal
Both B and C
Q.9
Duringthe phase transition, __________ changes.
Pressure
Volume
Temperature
All of the above
Q.10
The specific heat of saturated water vapour at 100°C is
∞
-ve
0
+ve
Q.11
Consider the reaction, C + O₂ ⇋ CO₂ ;ΔH = - 94 kcal. What will be the value of ΔH for the reaction CO₂ → C + O₂?
-94 kcal
+ 94 kcal
> 94 kcal
< -94 kcal
Q.12
In a working refrigerator, the value of COP is always
0
< 0
< 1
> 1
Q.13
Pick out the undesirable property for a good refrigerant.
High thermal conductivity
Low freezing point
Large latent heat of vaporisation
High viscosity
Q.14
The partial pressure of each constituent present in an alloy is __________ the total vapor pressure exerted by the alloy.
Less than
Equal to
More than
Either B or C; depends on the type of alloy
Q.15
Pick out the extensive property out of the following.
Surface tension
Free energy
Specific heat
Refractive index
Q.16
Entropy change of mixing two liquid substances depends upon the
Molar concentration
Quantity (i.e. number of moles)
Both A and B
Neither A nor B
Q.17
Ideal refrigeration cycle is
Same as Carnot cycle
Same as reverse Carnot cycle
Dependent on the refrigerant's properties
The least efficient of all refrigeration processes
Q.18
Specific volume of an ideal gas is
Equal to its density
The reciprocal of its density
Proportional to pressure
None of these
Q.19
With increase in temperature, the atomic heat capacities of all solid elements
Increases
Decreases
Remains unchanged
Decreases linearly
Q.20
When a gas is subjected to adiabatic expansion, it gets cooled due to
Decrease in velocity
Decrease in temperature
Decrease in kinetic energy
Energy spent in doing work
Q.21
Sound waves propagation in air exemplifies an __________ process.
Adiabatic
Isothermal
Isometric
None of these
Q.22
Which of the following exemplifies an adiabatic process?
Melting of ice
Condensation of alcohol vapor
Sudden bursting of a cycle tube
Evaporation of water
Q.23
4 kg moles of an ideal gas expands in vacuum spontaneously. The work done is
4 J
∞
0
8 J
Q.24
Which of the following units is not present in both the vapor compression refrigeration system and absorption refrigeration system ?
Expansion valve
Condenser
Refrigerator
Compressor
Q.25
Which is not constant for an ideal gas?
(∂P/∂V)
T
(∂V/∂T)
P
(∂P/∂V)
V
All of the above
Q.26
Isotherm on an enthalpy-concentration diagram, for an ideal solution will be a
Straight line
Sine curve
Parabola
Hyperbola
Q.27
Choose the condition that must be specified in order to liquify CO₂ (triple point for CO₂ is - 57°C and 5.2 atm).
Pressure must be kept below 5.2 atm
Temperature must be kept above - 57°C
Pressure must be kept below 5.2 atm. and temperature must be kept above 57°C
Pressure and temperature must be kept below 5.2 atm. and - 57°C respectively
Q.28
Entropy is a measure of the __________ of a system.
Disorder
Orderly behaviour
Temperature changes only
None of these
Q.29
Gibbs free energy per mole for a pure substance is equal to the
Latent heat of vaporisation
Chemical potential
Molal boiling point
Heat capacity
Q.30
Change of heat content when one mole of compound is burnt in oxygen at constant pressure is called the
Calorific value
Heat of reaction
Heat of combustion
Heat of formation
Q.31
Pick out the correct statement:
In an isothermal system, irreversible work is more than reversible work
Under reversible conditions, the adiabatic work is less than isothermal work
Heat, work, enthalpy and entropy are all 'state functions'
Matter and energy can not be exchanged with the surroundings in a closed system
Q.32
Translational kinetic energy of molecules of an ideal gas is proportional to (where, T = absolute temperature of the gas )
T
√T
T²
1/√T
Q.33
If two pure liquid constituents are mixed in any proportion to give an ideal solution, there is no change in
Volume
Enthalpy
Both A & B
Neither A nor B
Q.34
__________ calorimeter is normally used for measuring the dryness fraction of steam, when it is very low.
Bucket
Throttling
Separating
A combination of separating & throttling
Q.35
The necessary and sufficient condition for equilibrium between two phases is
The concentration of each component should be same in the two phases
The temperature of each phase should be same
The pressure should be same in the two phases
The chemical potential of each component should be same in the two phases
Q.36
Pick out the wrong statement.
System (of partially miscible liquid pairs), in which the mutual solubility increases with rise in temperature, are said to possess an upper consolute temperature
Systems, in which the mutual solubility increases with decrease in temperature, are said to possess lower consolute temperature
Nicotine-water system shows both an upper as well as a lower consolute temperature, implying that they are partially miscible between these two limiting temperatures
None of these
Q.37
Heat evolved/absorbed during conversion of a substance from one allotropic form to another is termed as the heat of
Fusion
Vaporisation
Transition
None of these
Q.38
When a system is in equilibrium for all possible processes, the differential or finite change of entropy is
< 0
> 0
= 0
None of these
Q.39
For a spontaneous process, free energy
Is zero
Increases
Decreases whereas the entropy increases
And entropy both decrease
Q.40
A large iceberg melts at the base, but not at the top, because of the reason that
Ice at the base contains impurities which lowers its melting point
Due to the high pressure at the base, its melting point reduces
The iceberg remains in a warmer condition at the base
All of the above
Q.41
Joule-Thomson co-efficient depends on the
Pressure
Temperature
Both A & B
Neither A nor B
Q.42
In Joule-Thomson porous plug experiment, the
Enthalpy does not remain constant
Entire apparatus is exposed to surroundings
Temperature remains constant
None of these
Q.43
Entropy, which is a measure of the disorder of a system is
Independent of pressure
Independent of temperature
Zero at absolute zero temperature for a perfect crystalline substance
All of the above
Q.44
Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The reatio of chemical potential to free energy of a pure substance at oconstant temperature and pressure is
0
1
∞
None of these
Q.45
One ton of refrigeration capacity is equivalent to the heat removal rate of
50 k cal/hr
200 BTU/hr
200 BTU/minute
200 BTU/day
Q.46
In jet refrigerators, the refrigerating fluid is practically always
Water
Ammonia
Freon
Brine
Q.47
High __________ is an undesirable property for a good refrigerant.
Specific heat
Latent heat of vaporisation
Viscosity
Specific vapor volume
Q.48
Joule-Thomson Co-efficient at any point on the inversion curve is
∞
+ ve
0
-ve
Q.49
Internal energy of an ideal gas
Increases with increase in pressure
Decreases with increase in temperature
Is independent of temperature
None of these
Q.50
In an ideal refrigeration cycle, the change in internal energy of the fluid is
+ve
-ve
0
Either of the above three ; depends on the nature of refrigerant
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