Q.1

Methane is mixed with stoichiometric proportion of oxygen and completely combusted. The number of additional specifications required to determine the product flow rate and composition is

  • 0
  • 1
  • 2
  • 3
Q.2

A vessel of volumem3 contains air which is saturated with water vapour. The total pressure and temperature arekPa and 20°C respectively. Assuming that the vapour pressure of water at 20°C is 2.kPa, the amount of water vapour (in kg) in the vessel is approximately

  • 17
  • 20
  • 25
  • 34
Q.3

A gaseous mixture containskg of N2,kg of O2 andkg of NH3. The mole fraction of oxygen is

  • 0.16
  • 0.33
  • 0.66
  • 0.47
Q.4

Pure oxygen is mixed with air to produce an enriched air containingvolume % of oxygen. The ratio of moles of air to oxygen used is

  • 1.72
  • 0.58
  • 0.5
  • 0.2
Q.5

According to the kinetic theory, the thermal conductivity of a monoatomic gas is proportional to

  • T
  • T0.5
  • T1.5
  • T2
Q.6

The depression in freezing point of a solution is

  • inversely proportional to the mass of solvent.
  • directly proportional to the mole of solute.
  • both (a) and (b).
  • neither (a) nor (b).
Q.7

The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. The temperature at which the above mixture will exert a pressure of one standard atm. is

  • less than 100°C
  • 100°C
  • between 100 and 110°C
  • 110.6°C
Q.8

Cv for monoatomic gases is equal to(where, R = gas constant)

  • R
  • 1.5 R
  • 2R
  • 3R
Q.9

Internal energy is independent of the __________ for an ideal gas.

  • pressure
  • volume
  • both (a) & (b)
  • neither (a) nor (b)
Q.10

Except for monoatomic gases, the molal heat capacity at constant volume for all gases is __________ Kcal/Kg mole.° K.

  • 3
  • > 3
  • < 3
  • < 1
Q.11

In a neutral solution

  • H+ ions are absent.
  • OH- ions are absent.
  • both H+ and OH- ions are present in very small but equal concentration.
  • none of these.
Q.12

1 bar is almost equal to __________ atmosphere.

  • 1
  • 10
  • 100
  • 1000
Q.13

With rise in temperature, the solubility of ammonia in water at a fixed pressure

  • increases
  • decreases
  • remains unchanged
  • increases exponentially
Q.14

The number of H+ in 1 c.c solution of pHis

  • 6.023 xl013
  • 6.023 x 1010
  • 6.023xl07
  • 1013
Q.15

Pick out the correct statement.

  • A substance existing above its critical temperature is called a saturated vapor.
  • A mixture of vapor gas is called saturated, if the equilibrium vapor pressure of the liquid is more than the partial pressure of the vapor at the same temperature.
  • Heat added to or given up by a substance at constant temperature is called the sensible heat.
  • The end points of a vapor-pressure vs. temperature curve are critical and triple points.
Q.16

Normality of a solution does not change with the increase in the

  • pressure
  • temperature
  • solute concentration
  • dilution of the solution
Q.17

The quantity of heat required to evaporate 1 kg of a saturated liquid is called

  • specific heat
  • 1 Kcal
  • sensible heat
  • latent heat
Q.18

Pick out the wrong unit conversion of thermal conductivity.

  • 1 BTU/ft2.hr.°F/ft = 1.488 kcal/m2. hr.°C/m
  • 1 BTU/ft2.hr.°F/inch = 1.488 kcal/m2. hr.°C/m
  • 1 kcal/m.hr.°C = 0.672 BTU/ft.hr.°F = 1.163 W/m. °K
  • 1 W/cm.°C = 85.985 kcal/m.hr.°C = 57.779 BTU/ft.hr.°F
Q.19

Cp - Cv, for an ideal gas is equal to

  • R
  • R/2
  • 2R
  • 3R
Q.20

An aqueous solution of 2.by weight H2SO4 has a specific gravity of 1.The composition expressed in normality is

  • 0.2500
  • 0.2528
  • 0.5000
  • 0.5055
Q.21

Which of the following ideal gas laws are not applicable to mixture of gases ?

  • Amgat's law
  • Dalton's law
  • Boyle's law & Charle's Law
  • none of these
Q.22

Othmer chart is useful in estimating the heat of

  • mixing
  • wetting
  • adsorption
  • none of these
Q.23

Volume occupied by one gm mole of a gas at S.T.P. is

  • 22.4 litres
  • 22400 litres
  • 22.4 c.c
  • 359 litres
Q.24

A solution of specific gravity 1 consists ofA by weight and the remaining B. If the specific gravity of A is 0.the specific gravity of Bis

  • 1.25
  • 1.3
  • 1.35
  • 1.2
Q.25

Unit of power is

  • joule
  • watt
  • joule/Second
  • both(b)&(c)
Q.26

__________ fuels require the maximum percentage of 'excess air' for complete combustion.

  • Solid
  • Liquid
  • Gaseous
  • Nuclear
Q.27

Heat of reaction is a function of the

  • pressure
  • temperature
  • both(a)&(b)
  • neither (a) nor (b)
Q.28

In __________ process, ions of salts react with water to produce acidity or alkalinity.

  • hydration
  • hydrolysis
  • electrolysis
  • dialysis
Q.29

Kopp's rule is useful for the determination of

  • molal heat capacities of gases.
  • heat capacities of solids.
  • activation energy.
  • heat capacities of gases.
Q.30

If the pH value of a solution changes by one unit, it implies that hydrogen ion concentration in the solution will change __________ times.

  • 10
  • 20
  • 70
  • 100
Q.31

The temperature at which a real gas obeys Boyle's law is termed as the

  • triple point
  • Boyle's temperature
  • eutectic point
  • inversion temperature
Q.32

Applicability of Claussius-Clapeyron equation is subject to the condition that the

  • vapor follows ideal gas law.
  • volume in the liquid state is negligible.
  • both (a) & (b)
  • neither (a) nor (b)
Q.33

The vapour pressure of water is given by, in Psat = A - (5000/T), where A is a constant, Psat is the vapour pressure in atm. and T is the temperature in K.The vapor pressure of water in atm. at 50°C is approximately

  • 0.07
  • 0.09
  • 0.11
  • 0.13
Q.34

The vapor pressure of water at 100°C is

  • 100N/m2
  • 76 cms of Hg
  • 13.6 cms of Hg
  • 760 mm wc
Q.35

Which of the following is insensitive to changes in pressure ?

  • Heat of vaporisation
  • Melting point
  • Heat of fusion
  • Both (b) and (c)
Q.36

Avogadro's number is equal to

  • 6.023 x 1023 molecules/kg.mole.
  • 6.023 x 1023 molecules/gm.mole.
  • 6.023 x 1016 molecules/kg.mole.
  • 6.023 x 1026 molecules/gm.mole.
Q.37

__________ equation relates latent heat and boiling point.

  • Antonie
  • Kistyakowsky
  • Kopp's
  • Trouton's
Q.38

Enthalpy of a vapor gas mixture may be increased by increasing the

  • temperature at constant humidity.
  • humidity at constant temperature.
  • temperature and the humidity.
  • all (a), (b) & (c).
Q.39

The gravimetric (i.e., by weight) composition of a vapor saturated gas is independent of the

  • nature of both the gas & the liquid.
  • temperature.
  • total pressure.
  • none of these.
Q.40

Pick out the wrong unit conversion.

  • 1 J = 1 W.Second = 107 ergs = 9.5 x 10-4 BTU = 0.2389 calorie
  • 1 Watt = 746 hp
  • -
  • -
Q.41

For the gaseous phase reaction, N2 + O22NO, ΔH = +kJ/kg. mole; the decomposition of NO is favoured by

  • increasing the concentration of N2.
  • decrease in temperature.
  • increase in pressure.
  • decrease in pressure.
Q.42

Variation of vapor pressure with temperature can be calculated using Clausius-Clapeyron equation, which assumes that the

  • vapor follows the ideal gas law.
  • molal latent heat of vaporisation is constant within the limited temperature range.
  • volume in the liquid state is negligible compared with that in the vapor state.
  • all (a), (b) & (c).
Q.43

The unit of Cp in S.I. units is

  • W/m2.°K
  • J/kg.°K
  • W/m.°K
  • J/m3. °K
Q.44

Dry air is a mixture of

  • vapors
  • gases
  • both (a) & (b)
  • neither (a) nor (b)
Q.45

A vapor whose partial pressure is less than its equilibrium vapor pressure is called the __________ vapor.

  • saturated
  • superheated
  • unsaturated
  • dry gaseous
Q.46

Pick out the wrong unit conversion.

  • 1 J = 1 W.Second = 107 ergs = 9.5 x 10-4 BTU = 0.2389 calorie
  • 1 Watt = 746 hp
  • -
  • -
Q.47

With rise in temperature, the heat capacity of a substance

  • increases
  • decreases
  • remains unchanged
  • either (a) or (b); depends on the substance
Q.48

1m3 is approximately equal to

  • 28 litres
  • 35 ft3
  • 4.5 litres
  • 4.5 ft3
Q.49

The heat capacity of a solid compound is calculated from the atomic heat capacities of its constituent elements with the help of the

  • Trouton's rule
  • Kopp's rule
  • Antonie equation
  • Kistyakowsky equation
Q.50

The vapour pressure of a solution (made by dissolving a solute in a solvent) is __________ that of the pure solvent.

  • less than
  • more than
  • equal to
  • either more or less; depends on the solvent
0 h : 0 m : 1 s