Q.1

The vapour pressure of a solution (made by dissolving a solute in a solvent) is __________ that of the pure solvent.

  • less than
  • more than
  • equal to
  • either more or less; depends on the solvent
Q.2

What is the simplest formula of a compound containingof element A (atomic weight =andof element B (atomic weight =?

  • AB3
  • A2B3
  • A2B
  • AB2
Q.3

At standard conditions,
N2 + 2O2 2NO2; ΔG° =kJ/mole
NO + O2 2NO2; ΔG° = -kJ/mole
The standard free energy of formation of NO in kJ/mole is

  • 15
  • 30
  • 85
  • 170
Q.4

At higher temperature, molal heat capacities of most of the gases (at constant pressure) __________ with increase in temperature.

  • increases
  • decreases
  • remains unchanged
  • increases linearly
Q.5

In the reaction, Ca + 2H2O = Ca(OH)2 + H2 ; what volume (c.c.) of hydrogen at STP would be liberated, when 8 gm of calcium reacts with excess water ? (atomic weight of calcium = 40)

  • 4480
  • 2240
  • 1120
  • 0.4
Q.6

Viscosity of 1 centipoise is equal to 1 centis-toke in case of

  • water
  • mercury
  • carbon tetrachloride
  • none of these
Q.7

Heat of neutralisation of HCl and NaOH is - 57.kJ/Kg mole. The heat of ionisation of water will be __________ kJ/Kg mole.

  • 57.46
  • -57.46
  • 114.92
  • -28.73
Q.8

pH value of H2SO4 (concentration) is

  • 5
  • 7
  • > 7
  • < 7
Q.9

How many phases are present at eutectic point ?

  • 1
  • 2
  • 3
  • unpredictable
Q.10

The increase in the temperature of the aqueous solution will result in decrease of its

  • weight % of the solute.
  • mole fraction of the solute.
  • molarity.
  • molality.
Q.11

The amount of Zn (atomic weight =required to formc.c. of H2 at N.T.P. on treatment with dilute H2SO4 will be __________ gm.

  • 0.065
  • 0.65
  • 6.5
  • 65
Q.12

Which of the following gases is the most soluble in water ?

  • NH3
  • CO2
  • H2S
  • CH4
Q.13

At higher temperature, molal heat capacities of most of the gases (at constant pressure) __________ with increase in temperature.

  • increases
  • decreases
  • remains unchanged
  • increases linearly
Q.14

pH value of a solution containing 1 gm of hydrogen ion per litre will be

  • 0
  • 1
  • 7
  • 10
Q.15

Claussius Clapeyron equation applies to the __________ process.

  • sublimation
  • melting
  • vaporisation
  • all (a), (b) & (c)
Q.16

In a chemical process, the recycle stream is purged for

  • increasing the product yield.
  • enriching the product.
  • limiting the inerts.
  • heat conservation.
Q.17

Unrestrained expansion of an ideal gas does not result in its cooling due to the reason that the gas molecules

  • do not lose energy on collision.
  • are above the inversion temperature.
  • do not exert attractive force on each other.
  • do work equal to loss in kinetic energy.
Q.18

The density of a gas 'X' is twice that of another gas 'Y'. If the molecular weight of gas 'Y' is 'M'; then the molecular weight of the gas 'X' will be

  • 2M
  • M/2
  • M
  • M/4
Q.19

If 1 Nm3 of O2 contains 'N' number of molecules, then number of molecules in 2Nm3 of SO2 will be

  • N
  • N/2
  • 2N
  • 4N
Q.20

__________ chart is a graph related to Antonie equation.

  • Ostwald
  • Cox
  • Mollier's
  • Enthalpy-concentration
Q.21

The viscosity of water at room temperature may be around one

  • centipoise
  • poise
  • stoke
  • both (b) &(c)
Q.22

Assuming applicability of ideal gas law, the pure component volume of the vapor in a saturated gas can be calculated from theoretical relationship. The volumetric composition of a vapor saturated gas is independent of the

  • nature of the liquid.
  • nature of the gas.
  • temperature of the liquid. id) total pressure.
Q.23

The most convenient way of expressing solution concentration is in terms of

  • mole fraction
  • normality
  • molality
  • molarity
Q.24

Degrees of freedom will be equal to the number of components for a system comprising of

  • only soluble liquid components.
  • partially miscible two liquid components system having two phases.
  • two liquid components and one solute (soluble in both the liquids).
  • none of these.
Q.25

Air at a temperature of 20°C andmm Hg pressure has a relative humidity of 80%. What is its percentage humidity ? Vapour pressure of water at 20°C is 17.5 mm Hg.

  • 80.38
  • 80
  • 79.62
  • 78.51
Q.26

Saturated solution of benzene in water is in equilibrium with a mixture of air and vapours of benzene and water at room temperature and pressure. Mole fraction of benzene in liquid is xB and the vapour pressures of benzene and water at these conditions are pvB and pvw respectively. The partial pressure of benzene in air-vapour mixture is

  • PvB
  • xB.PvB
  • (Patm - Pvw)xB
  • xB.Patm
Q.27

Unit of mass velocity is

  • kg/m . hr
  • kg/m2.hr
  • kg/hr
  • kg/m2
Q.28

The percentage ratio of the partial pressure of the vapor to the vapor pressure of the liquid at the existing temperature is

  • termed as relative saturation.
  • not a function of the composition of gas mixture.
  • called percentage saturation.
  • not a function of the nature of vapor.
Q.29

A perfectly insulated container of volume V is divided into two equal halves by a partition. One side is under vacuum, while the other side has one mole of an ideal gas (with constant heat capacity) atK. If the partition is broken, the final temperature of the gas in the container

  • will be greater than 298 K.
  • will be 298 K.
  • will be less than 298 K.
  • can not be determined.
Q.30

The heat capacity of most substances is greater for the __________ state.

  • solid
  • liquid
  • gaseous
  • none of these
Q.31

One mole of methane undergoes complete combustion in a stoichiometric amount of air. The reaction proceeds as CH4 + 2O2 → CO2 + 2H2O. Both the reactants and products are in gas phase. ΔH°298 = -kJ/mole of methane. If the average specific heat of all the gases/vapour isJ/mole.K, the maximum temperature rise of the exhaust gases in °C would be approximately equal to

  • 1225
  • 1335
  • 1525
  • 1735
Q.32

pH value of a solution containing equal concentration of hydroxyl and hydrogen ions will be

  • 0
  • 10
  • 7
  • 14
Q.33

With increase in temperature, the surface tension of water

  • increases
  • decreases
  • remains constant
  • increases linearly
Q.34

The temperature at which real gases obey the ideal gas law over a wide range of pressure is called the __________ temperature.

  • reduced
  • Boyle
  • critical
  • inversion
Q.35

As per Kirchoff s equation, the heat of reaction is affected by the

  • pressure
  • volume
  • temperature
  • molecularity
Q.36

The percentage ratio of the partial pressure of the vapor to the vapor pressure of the liquid at the existing temperature is

  • termed as relative saturation.
  • not a function of the composition of gas mixture.
  • called percentage saturation.
  • not a function of the nature of vapor.
Q.37

Enthalpy change resulting, when unit mass of solid is wetted with sufficient liquid, so that further addition of liquid produces no additional thermal effect, is called the heat of

  • mixing
  • adsorption
  • wetting
  • complete wetting
Q.38

The temperature at which real gases obey the ideal gas law over a wide range of pressure is called the __________ temperature.

  • reduced
  • Boyle
  • critical
  • inversion
Q.39

The total number of atoms in 8.5 gm of NH3 is __________ x 1023.

  • 9.03
  • 3.01
  • 1.204
  • 6.02
Q.40

Na2SO4. 10H2O crystals are formed by coolingKg ofby weight aqueous solution of Na2SO4. The final concentration of the solute in the solution is 10%. The weight of crystals is

  • 20
  • 32.2
  • 45.35
  • 58.65
Q.41

The atomic weight of helium is 4 times that of hydrogen. Its diffusion rate as compared to hydrogen will be __________ times.

  • 1/2
  • 4
  • 2
  • 1/4
Q.42

Elements in a periodic table are arranged in order of their

  • atomic number.
  • mass number.
  • atomic weight.
  • metallic characteristics.
Q.43

Which of the following gases will have the- highest kinetic energy per mole at the same pressure & temperature ?

  • Chlorine
  • Nitrogen
  • Ethane
  • All the gases will have the same KE
Q.44

kg of Na2SO4 (molecular weight =is present inkg of an aqueous solution. The solution is cooled such that.kg of Na2SO4 .10H2O crystals separate out. The weight fraction of Na2SO4 in the remaining solution is

  • 0.00
  • 0.18
  • 0.24
  • 1.00
Q.45

No cooling occurs, when an ideal gas undergoes unrestrained expansion, because the molecules

  • collide without loss of energy.
  • do work equal to loss in kinetic energy.
  • are above the inversion temperature.
  • exert no attractive force on each other.
Q.46

Osmotic pressure exerted by a solution prepared by dissolving one gram mole of a solute in 22.4 litres of a solvent at 0°C will be __________ atmosphere.

  • 0.5
  • 1
  • 1.5
  • 2
Q.47

For most salts, the solubility increases with rise in temperature, but the solubility of __________ is nearly independent of temperature rise.

  • sodium chloride
  • sodium carbonate monohydrate
  • anhydrous sodium sulphate
  • hypo
Q.48

Atmospheric pressure corresponds to a hydrostatic head of

  • 13.6 cms of Hg
  • 34 ft ofH2O
  • 1 metre of H2O
  • 13.6 metres of Hg
Q.49

With increase in the solute concentration, the specific heat of aqueous solutions

  • increases
  • decreases
  • remains unchanged
  • either (a) or (b); depends on the type of solution
Q.50

In general, the specific heats of aqueous solutions __________ with increase in the concentration of the solute.

  • increase
  • decrease
  • remain unchanged
  • none of these
0 h : 0 m : 1 s