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Polymer Engineering
Polymer Engineering Assessment
Quiz 1
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Q.1
Which of the following is not dependent on result of equilibrium condition of polymerization reaction?
a) degree of polymerization
b) chain length distribution
c) limiting monomer conversion
d) none of the mentioned
Q.2
How the increase in temperature to higher values, does affect the equilibrium state of propagation reaction?
a) shifts forward
b) shifts backwards
c) remains constant
d) none of the mentioned
Q.3
What is the value of overall rate of polymerization at ceiling temperature?
a) exceptionally high
b) exceptionally low
c) zero
d) cannot be determined
Q.4
What is the critical temperature Tc called, if ∆Hᵒ and ∆Sᵒ are both negative in radical polymerization?
a) ceiling temperature
b) floor temperature
c) theta temperature
d) all of the mentioned
Q.5
What is the critical temperature called, if ∆Hᵒ and ∆Sᵒ are both positive in radical polymerization?
a) ceiling temperature
b) floor temperature
c) theta temperature
d) all of the mentioned
Q.6
What is the approximate ceiling temperature of tetrahydrofuran?
a) 70ᵒC
b) 160ᵒC
c) 300ᵒC
d) none of the mentioned
Q.7
How does the viscosity of molten sulphur vary near 160ᵒC and above it?
a) goes minimum and then rises sharply
b) goes maximum and falls rapidly
c) remains constant
d) cannot be determined
Q.8
Which of the following does not affect the critical temperature, Tc?
a) heat of polymerization
b) conditions affecting monomer concentration
c) reaction medium
d) none of the mentioned
Q.9
What does the intersection point of kdp and kp[M] curves give, where kp and kdp are the rate constants of propagation and depropagation reaction, respectively, when kdp and kp[M] are plotted against temperature of reaction?
a) critical monomer concentration
b) critical ceiling temperature
c) kp/kdp
d) all of the mentioned
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